Archives
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 60 No. 1 (2025)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2025.1(60)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis and thermal stability of new heterocyclic and modified polymer compounds, as well as the characterization of nanostructured phosphate glasses and complex oxide systems. The regularities of complexation of lanthanides and transition metals, features of the structure of metallic melts, as well as new approaches in spectrophotometric and electrocatalytic analysis are highlighted.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 59 No. 1 (2024)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2024.1(59)
This issue is devoted to current research in the field of synthesis, properties, and applications of new functional materials, the development of modern methods of analysis, and the creation of biologically active compounds. It considers the synthesis of new fluorine-containing organic compounds, phosphates and borates, and coordination compounds of palladium and tantalum. The patterns of sorption processes for the determination of heavy metals, as well as the peculiarities of the structure of oxide melts and modified coal, are highlighted. New approaches in computational chemistry for assessing the conformational constraints of molecules are presented.
For teachers, researchers, graduate students, and students of chemical specialties.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 58 No. 1 (2023)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2023.1(58)
The issue presents the results of research in the field of synthesis, properties, and application of new functional materials, development of modern methods of analysis, and creation of biologically active compounds. It considers the issues of obtaining and characterizing catalysts, sensors, and sorbents. It highlights the patterns of complex formation, thermodynamic modeling, and the development of new approaches in microextraction.
The publication will be useful for teachers, researchers, graduate students, and students majoring in chemistry.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 57 No. 1 (2020)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2020.1(57)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis of complex phosphates in molten salts, neodymium cuprate solid solution substitutions, and liquid alloys of ternary systems. The regularities of heterocyclic compound reactions, the synthesis of triazole-containing macrocycles using click chemistry and DFT calculations, as well as the photochemical properties of modified polymers are highlighted. Special attention is paid to the coordination compounds of lanthanum, copper, and zinc, the creation of gas-sensitive semiconductor nanomaterials, and new approaches in fluorescent, pH-metric, and chemiluminescent analysis within micellar and solid-phase media.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 56 No. 1 (2019)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2019.1(56)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis of pyridine-substituted amino acids, the preparation of coumarin derivatives, and the modeling of thermodynamic properties of ternary system melts. The regularities of precipitation copolymerization, kinetic parameters of monomers, and polystyrene thermal stabilization processes are highlighted. Special attention is paid to the photovoltaic properties of bis-azomethines, the diffraction efficiency of polarization holograms based on azobenzene chromophores, and new approaches in voltammetric, fluorimetric, and sorption-spectroscopic determination of micro-amounts of elements and ions using modified electrodes and silica gels.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 55 No. 1 (2018)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2018.1(55)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the nomenclature of coordination compounds, regularities of melting and boiling points of simple substances, and modeling of thermochemical properties of ternary system melts. The processes of block copolymer acid hydrolysis, regularities of boronate synthesis via diol cleavage, and electrocrystallization of oxidized heterocycle forms are highlighted. Special attention is paid to transition metal and lanthanide complexes based on glyphosate and carbacylamidophosphates, adsorption semiconductor sensors, the development of holographic media, and the impact of macrocyclic copper compounds on the productivity of virus-infected plants.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 54 No. 2 (2017)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2017.2(54)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. A fundamental analysis of polymer chemistry development from organic molecules to macromolecular systems is presented, alongside the characterization of sol-gel processes in complex oxide systems and the features of heterocycle NMR spectroscopy. The regularities of the synthesis of new isoquinolones, flavone-based molecular tweezers for ATP detection, and coordination compounds of copper, palladium, and rare-earth elements are highlighted. Special attention is paid to the application of probabilistic neural networks and "electronic nose" technologies in food identification, the evaluation of oxidoreductase enzymatic activity within micellar media, and new approaches in sorption-photometric and iodometric determination of ions and toxic metals.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 53 No. 1 (2017)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2017.1(53)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis of novel heterocyclic systems, acrylonitriles, isoindoles, and electrophilic substitution in imidazopyridinium salts. The regularities of the sol-gel synthesis of cuprate solid solutions, the structure of substituted vanadates, and modeling of thermodynamic properties of liquid alloys are highlighted. Special attention is paid to ruthenium-nitrosyl complexes as nitric oxide donors, HTSC materials, gas sensors based on modified oxide nanomaterials, and cloud point preconcentration of amlodipine from biological liquids. A special paper in this issue marks the 100th anniversary of the birth of the prominent chemist F. S. Babichev.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 52 No. 1 (2016)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2016.1(52)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the fabrication and spectral-luminescence properties of binary phosphates and vanadates, thermodynamics and structure of ternary metallic melts, and the catalytic activity of systems in CO2 hydrogenation. The regularities of the synthesis of new chiral amino acid derivatives of triazoles, modified chromones, and block copolymer functionalization are highlighted. Special attention is paid to superconducting cuprates and nickelate solid solutions, polyurethane composites with heteropolynuclear complexes, uranyl ion interaction with triazole-based ligands, chemical modification of carbon fiber, and portable colorimetric and chromatographic indicator systems for environmental and pharmaceutical monitoring.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 51 No. 1 (2015)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2015.1(51)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis of novel pyranochromenediones, Michael and Michael-Diels-Alder adducts based on aminoisoindole, and the thermochemistry of iron-antimony alloy formation. The regularities of gas-phase modification of activated carbon and the catalytic activity of supported systems in $CO_2$ hydrogenation and alcohol dehydration reactions are highlighted. Special attention is paid to the photovoltaic and optical properties of film composites, coordination compounds of palladium, copper, and uranyl with nitrogen-containing heterocycles, quantum-chemical modeling of substituted styrenes, as well as new sorption, spectrophotometric, and luminescent indicator systems for the determination of iodine, fluoride, thiocyanates, and trace heavy metals in environmental and biological objects.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 50 No. 1 (2014)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2014.1(50)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. Comprehensive reviews on modern analytical methods for benzophenones, oxalates, tartrates, and diuretics in biological and pharmaceutical objects are presented, alongside applications of electron probe microanalysis for phosphorus determination. The regularities of the Mannich reaction in isocoumarins, kinetics of catalytic processes, CO2 methanation, and the thermochemistry of iron-lanthanide alloy formation are highlighted. Special attention is paid to the influence of heteropolynuclear complexes on cross-linked polyurethane structures, fluorescent properties of phosphorus-containing dendrimers, spectral behavior of flavone and coumaroyl-benzopyrylium chromophore systems, as well as new approaches in hollow-fiber microextraction and sorption preconcentration of trace elements and toxicants on chemically modified silica gels and carbon materials.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 49 No. 1 (2013)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2013.1(49)
This issue is dedicated to current research in the field of synthesis, modification, and application of new functional materials, development of modern methods of chemical analysis, and creation of biologically active substances. The papers discuss the synthesis and heterovalent substitution regularities in high-temperature superconducting cuprate systems and lanthanum nickelates, alongside the kinetics of gas-phase bromination of activated carbon and catalytic CO oxidation over carbon nanotubes. New approaches in the synthesis of potential pyrimidine-based antifolates, sulfamoyl derivatives of isocoumarins, isoindoles, and modified coumarins are highlighted. Special attention is paid to lanthanide coordination compounds with phosphorylated ligands, binuclear copper, uranyl, and palladium complexes based on substituted triazoles, the electronic structure of cyanine dyes, as well as novel sorption, capillary, and visual test systems for the determination of mercury, iodine, thiocyanates, EDTA, and menthol in pharmaceuticals and plant materials.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 48 No. 1 (2010)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2010.1(48)
This issue focuses on the structural features, synthesis methods, and practical applications of novel inorganic, organic, and polymer materials, alongside regularities of sorption and micellar interactions in analytical chemistry. The volume features research on high-temperature superconductors, phase formation kinetics in complex oxide and phosphate systems, and advanced approaches to the microwave synthesis of biomaterials. It highlights the targeted synthesis of functionalized organic compounds, studies on transition metal coordination complexes with nitrogen-containing heterocycles, and the structural modeling of nanocomposites. Significant attention is dedicated to the development of sensitive analytical methods for environmental and food safety control using modern preconcentration systems, modified sorbents, and surfactants.
For university lecturers, researchers, postgraduate students, and higher education applicants.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 47 No. 2 (2008)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2008.2(47)
This issue is dedicated to current research in the synthesis, modification, and application of novel functional materials, thermodynamics of multicomponent systems, as well as the development of modern methods for chemical analysis, environmental monitoring, and the design of biologically active substances.
The volume features research in the coordination chemistry of lanthanides and transition metals (including dinuclear nickel, copper, and heterometallic complexes), alongside the targeted synthesis of functionalized organic compounds and phosphoryl-containing ligands. Significant attention is paid to physicochemical processes on the surface of heterogeneous catalysts, thermodynamic modeling of melts and phase diagrams of complex systems, and the properties of high-temperature superconductors. A specialized series of papers addresses the development of efficient cloud-point and sorption preconcentration methods for metals, the influence of surfactants on atomic absorption determination, and the evaluation of toxic organic pollutants in the environment.
For lecturers, researchers, postgraduate, and undergraduate students in chemistry.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 46 No. 1 (2008)UDC 54(051)
DOI: https://doi.org/10.17721/1728-2209.2008.1(46)
This issue is dedicated to current research in the synthesis, modification, and application of novel functional materials, thermodynamics of multicomponent systems, as well as the development of modern methods for chemical analysis, environmental monitoring, and the design of biologically active substances. A special section of this volume is dedicated to the 90th birth anniversary of the prominent physical chemist, Professor Georgiy Ivanovych Batalin, highlighting the significant achievements of the Department of Physical Chemistry.
The volume features key studies on the thermodynamic properties, structure, and phase formation kinetics of liquid alloys (particularly those containing aluminum, silicon, lanthanides, and noble metals), alongside the physicochemical characteristics of multicomponent slag systems used in welding technologies. It highlights the development of semiconductor and zeolite-based gas-sensitive sensor materials, novel carbon-supported catalytic systems, and the electrochemical behavior of non-aqueous electrolytes. Significant attention is also paid to the targeted design of binuclear pyrazole-containing ligands for enzymatic inhibition, simulation of homogeneous crystallization processes, and the formation of metastable states of substances.
For lecturers, researchers, postgraduate, and undergraduate students in chemistry.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 45 No. 2 (2007)This issue is dedicated to current research in the synthesis, modification, and application of novel functional materials, thermodynamics of multicomponent systems, as well as the development of modern methods for chemical analysis, environmental monitoring, and the design of biologically active substances.
The volume highlights the design and evaluation of catalytic and sensor materials, specifically loaded oxide systems for carbon monoxide oxidation and long-term stable hydrogen adsorption semiconductor sensors. It features studies on the synthesis of high-temperature superconductors, metal-containing supramolecular composites of fullerene, and coordination complexes of uranyl and zirconium. A substantial portion of the issue is focused on polymer chemistry, including photoconductive copolymers and the radical polymerization of functional methacrylates. Great practical value lies in the investigations of phase separation in surfactant systems and the development of highly sensitive sorption and cloud-point extraction methods for the concentration and determination of heavy and toxic metals (such as thallium, mercury, iron, and platinum-group metals) to benefit environmental monitoring and industrial analysis.
For lecturers, researchers, postgraduate, and undergraduate students in chemistry.
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Bulletin of Taras Shevchenko National University of Kyiv. Chemistry
Vol. 44 No. 1 (2007)The materials of international seminar “Modern problems of coordination chemistry (Kyiv, Desember 12–14, 2004) hes been pablished.
For lecturers, scientists, aspirants and students.
This issue is dedicated to current research in the synthesis, modification, and application of novel functional materials, coordination chemistry of polynuclear systems, as well as the development of modern methods for studying magnetic properties and the design of molecular magnets.
The volume highlights carbacylamidophosphates of metals as structural building blocks for the design of polynuclear coordination compounds, the hierarchical self-assembly of nano-sized exchange clusters, and novel approaches to the synthesis of heteropolynuclear complexes. Significant attention is paid to high-spin coordination compounds of 3d-metals as perspective molecular magnets, ferromagnetic complexes of azomethine ligands, and the coordination chemistry of metals with amines, amides, hydrazides, and hydrazones. A special focus is placed on the application of electron paramagnetic resonance (EPR) spectroscopy to study spin-spin interactions between Cu(II) atoms in polynuclear complexes.
For lecturers, researchers, postgraduate, and undergraduate students in chemistry.
