SYNTHESIS AND INVESTIGATIONS OF ANIONIC LANTHANIDE COMPLEXES WITH N- N-(DIALLILAMINOPHOSPHORYL)-4- METHYLBENZENESULFONAMIDE

UDC 546.650+543.42

Authors

  • I. Olyshevets, Student Taras Shevchenko National University of Kyiv image/svg+xml
  • N. Kariaka, PhD student Taras Shevchenko National University of Kyiv image/svg+xml
  • V. Trush, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • T. Sliva, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • V. Amirkhanov, DSc (Chemistry) Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

sulfonylamidophosphates, lanthanides, coordination compounds

Abstract

The new sulfonamidephosphate type ligand (HL=п-CH3(C6H4)SO2N(H)P(O)(N(H)CH2CH=CH2)2 ) and its sodium salt (NaL) have been synthesized. Some of lanthanide (III) coordination compounds of the general formula Na[LnL4] ( where Ln = La, Nd, Eu, Tb) have been obtained and characterized by means of 1Н NMR, IR and UV-Vis- spectroscopy. The bidentate coordination of the ligand via the oxygens of phosphoryl and sulphonyl has been concluded.

References

1. Near-infrared fluorescent materials for sensing of biological targets / C.L. Amiot, S. Xu, S. Liang et al. // Sensors. – 2008. – 8. – P. 3082–3105.

2. Каткова М.А. Координационные соединения редкоземельных ме-таллов с органическими лигандами для электролюминесцентных дио-дов / М.А. Каткова, А.Г. Витухновский, Н.М. Бочкарев // Успехи химии. – 2005. – 74, № 12. – С. 1193-1215.

3. Energetic Ionic Liquids based on Lanthanide nitrate Complex Anions / G.-H. Tao, Y. Huang, J.A. Boatz et al. // Chem. Eur. J. – 2008. – Vol. 14, № 35. – P. 11167–11173.

4. Шварценбах Г. Комплексонометрическое титрование / Г. Швар-ценбах, Г. Флашка. – М.: Химия, 1970. – 360 с.

5. Определение химического строения координационных соедине-ний лантаноидов на основе их спектров поглощения / К.Б. Яцимирский, Н.К. Давиденко, Н.А. Костромина, Т.В. Терновая // Теоретическая и экспериментальная химия. – 1965. – 1, №1. – С. 100–105.

Downloads

Published

2013-11-01

Issue

Vol. 49 No. 1 (2013): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2013 І. Олишевець, студент, Н. Каряка, асп., В. Труш, канд. хім. наук, Т. Слива, канд. хім. наук, В. Амірханов, д-р хім. наук

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

SYNTHESIS AND INVESTIGATIONS OF ANIONIC LANTHANIDE COMPLEXES WITH N- N-(DIALLILAMINOPHOSPHORYL)-4- METHYLBENZENESULFONAMIDE: UDC 546.650+543.42. (2013). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 49(1), 11-13. https://chemistry.bulletin.knu.ua/article/view/8434

Most read articles by the same author(s)