SYNTHESIS AND INVESTIGATION OF LANTHANIDES TETRAKIS-COMPLEXES WITH DIMETHYL-P-TOLUILSULPHONILAMIDOPHOSPHATE

UDC 546.65+539.26+535.37

Authors

  • T. Kratchko, Student Taras Shevchenko National University of Kyiv image/svg+xml
  • V. Trush, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • T. Sliva, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • E. Trush, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • I. Konovalova, PhD student Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

-

Abstract

The raw of lanthanide (III) coordination compounds with dimethyl-p-toluilsulphonilamidophosphate of the composition Na[LnL4],
where Ln = La-Lu (except Pm); HL = p-CH3(C6H4)SO2N(H)P(O)(OCH3)2 – dimethyl-p-toluylsulphonylamidophosphate have been synthesized and isolated in crystalline state. Based on the IR spectra the bidentate coordination of ligand L
- via the oxygens of phosphoryl and
sulphonyl has been concluded. The complex Na[LaL4] was investigated by means X-ray diffraction. The coordination sphere of lanthanum atom has been characterized as distorted dodecahedron. 

References

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Published

2010-09-06

Issue

Vol. 48 No. 1 (2010): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2010 Т. Крачко, студ., В. Труш, канд. хім. наук, Т. Слива, канд. хім. наук, Є. Труш, канд. хім. наук, І. Коновалова, асп.

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How to Cite

SYNTHESIS AND INVESTIGATION OF LANTHANIDES TETRAKIS-COMPLEXES WITH DIMETHYL-P-TOLUILSULPHONILAMIDOPHOSPHATE: UDC 546.65+539.26+535.37. (2010). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 48(1), 36-38. https://chemistry.bulletin.knu.ua/article/view/8316

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