DIFFERENT-LIGAND COMPLEXES OF SOME TRANSITION METALS ON THE SURFACE OF SILICA GELS, MODIFIED NITROGEN-CONTAINING LIGANDS

UDC 541.183'49:546.732'742'776

Authors

  • O. Tsyganovich, Cand. Sci. (Chem.) F.D. Ovcharenko Institute of Biocolloidal Chemistry image/svg+xml
  • O. Siryk, Student Taras Shevchenko National University of Kyiv image/svg+xml
  • A. Trokhymchuk, DSc (Chemistry) Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

different-ligand complexes, transition metals, diffuse reflection spectroscopy

Abstract

The peculiarities of the heteroligand complexes (HLC) formation of Ni (II), Co (II) and Mo (VI) on silica gel with chemically bounded aminopropyl (C-NH2) and ethylenediamine groups (C-en), and silica gel with impregnated polyhexamethyleneguanidine chloride (C-PHMG) with unitiol and Pyrocatechol Violet were studied. According to the data of DRS analysis composition of the complexes were found, and by comparing of the diffuse reflecta spectra of adsorbates with electronic absorption spectra of complexes with these reagents in solution it was shown that the heteroligand complexes on the surface are similar to the complexes in solution. The stability of heteroligand complexes depends on the method of synthesis was studied. The possibility of using of the obtained colored HLC to test-, sorption-spectrometric and colorimetry methods of analysis was shown.

References

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Published

2013-11-01

Issue

Vol. 49 No. 1 (2013): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2013 О. Циганович, канд. хім. наук, О. Сірик, студент, А. Трохимчук, д-р хім. наук

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

DIFFERENT-LIGAND COMPLEXES OF SOME TRANSITION METALS ON THE SURFACE OF SILICA GELS, MODIFIED NITROGEN-CONTAINING LIGANDS: UDC 541.183’49:546.732’742’776. (2013). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 49(1), 27-30. https://chemistry.bulletin.knu.ua/article/view/8443

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