THE INFLUENCE OF SURFACTANTS ON THE FLAME ATOMIC ABSORPTION DETERMINATION OF HEAVY METALS

UDC 543.422, 661.183.1

Authors

  • S. Lelyushok, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • M. Ishchenko, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • S. Kulichenko, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • V. Doroschuk, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

-

Abstract

The influence of the different type of surfactants on the analytical signal of flame atomic absorption determination of heavy metals was investigated. The possibility of the decrease of the limit determination of lead, manganese and cadmium at the expense of modificating actions of non-ionic surfactants was shown. On the example of nickel and lead the influence of charge of the surfactant and "magical" action of the critical micelle concentration on the detection sensitivity of atomic absorption determination of heavy metals was shown.

References

1. Абрамзон, А.А., Зайченко, Л.П., Файнгольд, С.И. Поверхностно-активные вещества. Синтез, анализ, применение // Под. ред. Абрамзо-на А.А. – Л.: Химия, 1988. –200 с.

2. Дорощук, В.О., Куліченко, С.А. Концентрирование кадмия фазами неионного ПАВ ОП 10 при темпера-туре помутнения // Журн. аналит. хим. 2005. – Т. 60, №5. –С. 458-463.

3. Корестелев, П.П. Приготовление растворов для хими-ко аналитических работ. М.: Изд-во АН СССР, 1964. 311 с.

4. Набиванець, Б.Й., Сухан, В.В., Калабіна, Л.В. Аналітична хімія навко-лишнього середовища. -К.: Либідь, 1996. –304 с.

5. Саввин, С.Б., Чернова, Р.К., Штыков, С.Н. Поверхностно-активные вещества –М.: Наука, 1991. – 251 с.

6. Штыков, С.Н. Поверхностно-активные вещества в анализе. Основные достижения и тенденции развития // Журн. аналит. химии. – 2000. – Т. 55, №7. – С. 679-686.

7. Chen, J., Xiao, S., Wu, X., Fang, K., Liu, W. Determination of lead in water samples by graphite furnace atomic absorption spectrometry after cloud point extraction // Talanta. – 2005. – Vol.67, №5. –P. 992-996.

8. Coelho, L.M., Arruda, M.A. Preconcentration procedure using cloud point extraction in the precence of electrolyte for cadmium determination by flame atomic absorption spectrometry // Spectrochimica Acta. - 2005. - Vol. 60, - P. 473-478.

9. Hinze, W.L. Pramauro, E. A critical review of surfactant-mediated phase separations (cloud point extractions): theory and applications // CRC Crit. Rev.Anal.Chem. 1993. Vol. 24, №2. – P. 133-177.

10. Ohashi, A., Ito, H., Kanai, Н., Imura, H., Ohashi, K. Cloud point extraction of iron(III) and vanadium(V) using 8-quinolinol derivatives and Triton X-100 and determination of 10−7 mol dm−3 level iron(III) in riverine water reference by a graphite furnace atomic absorption spectroscopy // Talanta. – 2005. – Vol. 65, №2. P. 525 530.

11. Quina, F.H., Hinze, W.L. Surfactant-mediated cloud point extractions: an environmentally benign alternative separation approach // Ind.Eng.Chem.Res. 1999. Vol. 38, №11. – P. 4150-4168.

Downloads

Published

2009-07-21

Issue

Vol. 47 No. 2 (2008): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2009 С. Лелюшок, канд. хім. наук, М. Іщенко, канд. хім. наук, С. Куліченко, канд. хім. наук, В. Дорощук, канд. хім. наук

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

THE INFLUENCE OF SURFACTANTS ON THE FLAME ATOMIC ABSORPTION DETERMINATION OF HEAVY METALS: UDC 543.422, 661.183.1. (2009). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 47(2), 44-46. https://chemistry.bulletin.knu.ua/article/view/8420

Most read articles by the same author(s)

1 2 > >>