RED-OX PROPERTIES AND CATALYTIC ACTIVITY IN CO OXIDATION COPPER-CONTAINING ZEOLITE SYSTEMS

UDC 541.128.13

Authors

  • L. Oleksenko, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • Yue Chen, PhD student Taras Shevchenko National University of Kyiv image/svg+xml
  • I. Kuzmich, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

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Abstract

The catalytic activity in CO oxidation of 10% Cu-zeolite systems after their formation in various temperature intervals (Tform=20-350oC and Tform=20-500oC) was investigated. It was established that activity of loaded 0% Cu-zeolite systems (Tform=20-350oC) decrease in the order: Cu-NaZSM-5 (47) > Cu-NaX > Cu-NaZSM-5 (69) > Cu-Na,K-ERI > Cu-NaZSM-5 (37) > Cu-NaA > Cu-NaM. It was shown, that activity of zeolite systems mostly determined by the quantity of active centres – Cu2+ cations which practically haven't interaction with carrier surface, surround by oxygen ions with high reaction ability and easy undergo red-ox processes (T < 300oC).

References

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Published

2007-05-18

Issue

Vol. 46 No. 1 (2008): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2007 Л. Олексенко, канд. хім. наук, Юе Чень, асп., И. Кузьмич, канд. хім. наук

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

RED-OX PROPERTIES AND CATALYTIC ACTIVITY IN CO OXIDATION COPPER-CONTAINING ZEOLITE SYSTEMS: UDC 541.128.13. (2007). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 46(1), 26-28. https://chemistry.bulletin.knu.ua/article/view/8376

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