SYNTHESIS AND STRUCTURE CHARACTERIZATION OF (TRITOLYLSTANNYLTHIO)(TRIPHENYLSTANNYL)METHYL TRIPHENYLSTANNANECARBODITHIOATE

Authors

  • I. Kulai Paul Sabatier University – Toulouse III, Toulouse, France , Taras Shevchenko National University of Kyiv image/svg+xml
  • S. Mazières Paul Sabatier University – Toulouse III, Toulouse, France
  • V. Kovtunenko Taras Shevchenko National University of Kyiv image/svg+xml
  • Z. Voitenko Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

organotin, thiocarbonyl, crystal structure, triphenylstannanecarbodithioate

Abstract

The title compound Ph3SnCS2CH(SSnTol3)SnPh3 has been isolated as major product after the attempted alkylation of lithium triphenylstannanecarbodithioate by tri(p-tolyl)tin chloride in THF as solvent and characterized by NMR spectroscopy and elemental analysis. The pink crystals of this compound have been grown from pentane/dichloromethane solution. The solid state structure has been established by X-ray crystallography analysis.

References

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Published

2015-11-10

Issue

Vol. 51 No. 1 (2015): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2015 І. Кулай, С. Мазьєр, В. Ковтуненко, З. Войтенко

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

SYNTHESIS AND STRUCTURE CHARACTERIZATION OF (TRITOLYLSTANNYLTHIO)(TRIPHENYLSTANNYL)METHYL TRIPHENYLSTANNANECARBODITHIOATE. (2015). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 51(1), 66-68. https://chemistry.bulletin.knu.ua/article/view/8558

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