THE METHANATION OF CO2 OVER CO-NI/AL2O3 CATALYSTS AT ATMOSPHERIC PRESSURE

UDK 544.47:544.344 + 546.73 + 546.74 + 546.264-31

Authors

  • K. Nifantiev, PhD student Taras Shevchenko National University of Kyiv image/svg+xml
  • O. Byeda, PhD Taras Shevchenko National University of Kyiv image/svg+xml
  • E. Ischenko, Professor Taras Shevchenko National University of Kyiv image/svg+xml
  • A. Mischanchuk, Engineer Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

methanation, carbon dioxide, supported catalysts, cobalt-nickel catalysts

Abstract

The methanation of carbon dioxide under atmospheric pressure over a Co-Ni/Al2O3 catalyst containing 5 wt% of metals prepared by the impregnation method was studied. Temperature of 95% conversion CO2 for all examined catalysts falls into range 320–450°C at conditions of SV 100 ml/min, 0.1 MPa pressure, and composition of feeding gas mixture CO2 – 2%, H2 – 55%, He – 43%. Methane selectivity was sufficiently high – up to 98%.

References

1. Recent advances in catalytic hydrogenation of carbon dioxide / Wei Wang, Shengping Wang, Xinbin Ma et al. // Chem. Soc. Rev. – 2011. – V. 40. – P. 3369–4260.

2. Wei Wang. Methanation of carbon dioxide: an overview / Wei Wang, Jinlong Gong // Front. Chem. Sci. Eng. – 2011. – V. 5(1). – P. 2–10.

3. Heterogeneous catalytic CO2 conversion to value–added hydrocarbons / Robert W. Dorner, Dennis R. Hardy, Frederick W. Williams et al. // Energy Environ. Sci. – 2010. – V. 3. – P. 884–890.

4. Richardson J.T. Improved Sabatier reactions for in situ resource utilization on Mars missions / J.T. Richardson // In Institute for Space Systems Operations – 1999–2000 Annual Report. – 2000. – P. 84–86.

5. Materials for global carbon dioxide recycling / K. Hashimoto, M. Yamasaki, S. Meguro et al. // Corros. Sci. – 2002. – V. 44. – P. 371–386.

Downloads

Published

2014-11-13

How to Cite

THE METHANATION OF CO2 OVER CO-NI/AL2O3 CATALYSTS AT ATMOSPHERIC PRESSURE: UDK 544.47:544.344 + 546.73 + 546.74 + 546.264-31. (2014). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 50(1), 64-66. https://chemistry.bulletin.knu.ua/article/view/8531

Most read articles by the same author(s)