SORPTION OF PHOSPHOROUS DERIVATIVES OF CYANINE DYES ONTO FILMS BASED ON SILICA AND CATION-EXCHANGE POLYELECTROLYTES

UDC: 543.4:543.544

Authors

  • A. Motorina, PhD student Taras Shevchenko National University of Kyiv image/svg+xml
  • O. Nadzhafova, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • M. Mazières, Research Officer Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

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Abstract

It was demonstrated the possibility of modification of the composite films based on silica and cation-exchange polyelectrolytes with dioxyazaphosphocane derivatives of cyanine dyes. Optimal conditions of the dyes immobilization were found. The modified films were shown to be perspective for sorption-luminescent determination of alkaline-earth metal ions i.e. Calcium.

References

1. Березов, Т.Т., Коровкин, Б.Ф. Биологическая химия. – М., 1998.

2. Коган, И.М. Химия красителей. – М., 1956.

3. Наджафова, О. Ю., Дроздова, М. В., Чурилова, И. В. Влияние поверхностно-активных веществ на сорбционные свойства композитных пленок на основе оксида силиция и органического катионообменника, полученных по золь-гель технологии // Укр. хим. журн. - 2007. - Т. 73, №4. - С. 98-102.

4. Brinker, C.I., Scherer, G.W. Sol-gel science: the physics and chemistry of sol-gel processing. – San Diego Academic Press, 1990.

5. Citterio, D., Omagari, M., et al. Chromogenic betaine lariats for highly selective Calcium ion sensing in aqueous environment // Anal. Chem. Acta. - 2004. - Vol. 504. - P. 227-234.

6. Easwaran Arunkumar, Forbes, Ch. C., Smith, B.D. Improving the properties of organic dyes by molecular encapsulation // Eur.J.Org.Chem. - 2005. - P. 4051-4059.

7. Jerónimo, P.C.A., Araújo, A.N., et al. Optical sensors and biosensors based on sol-gel films // Talanta. – 2007, №72. - P. 13-27.

8. Jin, Ji, Rozenweig, Z. Fiber optic pH/Ca2+ fluorescence microsensor based on spectral processing of sensing signals // Anal. Chem. Acta - 1999. - Vol. 397. - P. 93-102.

9. Liqiu Wang, Xiaojun Peng, et al. New near-infrared indocyanines and their spectral properties in SiO2 sol-gel // Dyes And Pigments. – 2004. - №61. - P. 103-107.

10. Mazieres, M. R., Duprant, C., et al. Synthesis and characterization of new phosphonate labeled cyanines // Dyes And Pigments. – 2007. - №74. - P. 404-409.

11. Mazieres, M. R., Wetz, F., et al. New phosphorus podands labeled by a cyanine probe: synthesis and fluorescence enhancement with cation complexation // Dyes And Pigments. – 2003. - №56. - P. 231-238.

12. Raman, N.K., Anderson, M.T., Brinker, C.J. Template-based approaches to the preparation of amorphous, nanoporous silicas // Chem. Mater. - 1996. - Vol. 5. - P. 1682-271.

13. Schulz-Ekloff, G., Wöhrle, D., et al. Chromophores in porous silicas and minerals: preparation and optical properties // Micropor. And Mesopor. Mater. – 2002. - №51. - P. 91-138.

14. Watanabe, T., Zhou, H.S., et al. Synthesis and nonlinear optical susceptibility of cyanine dye J-aggregate doped silica film // J.Of Sol-Gel Science And Technology. - 2000. - Vol. 19, №1-3. - P. 257-261.

15. Williford, R.E., Li, X.S., et al. Mechanical stability of templated mesoporous silica thin films // Micropor. And Mesopor. Mater. – 2005. - №85. - . P. 260-266.

Published

2009-07-21

How to Cite

SORPTION OF PHOSPHOROUS DERIVATIVES OF CYANINE DYES ONTO FILMS BASED ON SILICA AND CATION-EXCHANGE POLYELECTROLYTES: UDC: 543.4:543.544. (2009). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 47(2), 21-23. https://chemistry.bulletin.knu.ua/article/view/8409

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