SYNTHESIS, CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A DINUCLEAR NICKEL(II) COMPLEX WITH 3-[(1E)-N-HYDROXYETHANIMIDOYL]-4-METHYL-1H-PYRAZOLE-5-CARBOXYLIC ACID

UDC 546.74: 538

Authors

  • L. Penkova, Engineer Taras Shevchenko National University of Kyiv image/svg+xml
  • V. Pavlenko, Cand. Sci. (Chem.) Taras Shevchenko National University of Kyiv image/svg+xml
  • I. Fritsky, DSc (Chemistry) Taras Shevchenko National University of Kyiv image/svg+xml

Keywords:

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Abstract

The complex [Ni2(PzOxCA–2Н)2(Py)4]·2Н2О based on novel pyrazolate ligand 3-[(1E)-N-hydroxyethanimidoyl]-4-methyl-1H-pyrazole-5-carboxylic acid (PzOxCA) has been synthesized and its crystal structure has been determined by X-ray single crystal analysis. Magnetic susceptibility measurements in the temperature range 1.8 – 300 K revealed antiferromagnetic exchange coupling between nickel(II) ions (J = –15,23 cm–1).

References

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Published

2009-07-21

Issue

Vol. 47 No. 2 (2008): Bulletin Taras Shevchenko National University of Kyiv. Chemistry

Section

Articles

License

Copyright (c) 2009 Л. Пенкова, інженер, В. Павленко, канд. хім. наук, І. Фрицький, д-р хім. наук

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This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

SYNTHESIS, CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A DINUCLEAR NICKEL(II) COMPLEX WITH 3-[(1E)-N-HYDROXYETHANIMIDOYL]-4-METHYL-1H-PYRAZOLE-5-CARBOXYLIC ACID: UDC 546.74: 538. (2009). Bulletin of the Taras Shevchenko National University of Kyiv. Chemistry, 47(2), 18-21. https://chemistry.bulletin.knu.ua/article/view/8408

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